Difference Between 316 and 316L Stainless Steel

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“Unlock the Secrets: Choosing Between Stainless Steel 316 and 316L Made Simple!”

Stainless steel, a highly durable and corrosion-resistant material, is utilized in a myriad of applications ranging from heavy industry to domestic items. Among its various grades, 316 and 316L stainless steel are two of the most commonly used, especially in environments exposed to corrosive elements. This guide aims to delineate the differences between 316 and 316L stainless steel, helping you understand their unique properties, applications, and why choosing the right type matters for specific projects. By exploring their chemical composition, mechanical properties, and typical uses, this guide provides foundational knowledge for making informed decisions in selecting the appropriate grade of stainless steel for various applications.

Definitions Of Stainless Steel 316 And 316L

Stainless Steel 316

Type 316 stainless steel, also known by the UNS designation S31600, is an austenitic chromium-nickel stainless steel which includes an addition of molybdenum. The molybdenum presence in Type 316 enhances its corrosion resistance, particularly against chlorides and other industrial solvents. This makes it exceedingly suitable for use in environments where exposure to corrosive elements is a significant concern, such as in marine or coastal settings. Furthermore, Type 316 exhibits excellent tensile strength, resistance to pitting, and maintains its integrity even at high temperatures.

Stainless Steel 316L

Type 316L stainless steel, where ‘L’ stands for ‘low carbon,’ is the low carbon version of Type 316. Classified under UNS S31603, Type 316L contains reduced carbon content compared to its counterpart. This reduction in carbon is pivotal as it minimizes the risk of carbide precipitation during welding. Carbide precipitation can occur in the 316 type when exposed to high temperatures, which can lead to degradation of the steel at the grain boundaries, thus compromising its overall strength and corrosion resistance.

The primary advantage of Type 316L over Type 316 is its enhanced weldability owing to its lower carbon content. This characteristic is particularly beneficial in applications where the material is susceptible to corrosion after welding, a common scenario in the construction of pipelines and other welded structures. Moreover, Type 316L maintains most of the same mechanical properties of Type 316, including its resistance to corrosion and oxidation. However, it is important to note that the lower carbon content may make Type 316L slightly less resistant to high temperatures compared to Type 316.

What Are the Equivalents of 316 and 316L Stainless Steel?

International Equivalents

Type 316 stainless steel, also known by its UNS designation S31600, is an austenitic chromium-nickel stainless steel that contains an addition of molybdenum. The molybdenum in Type 316 stainless steel increases its corrosion resistance, particularly against chlorides and other industrial solvents. This grade is often utilized in environments exposed to harsh chemicals and more saline conditions like coastal areas.

Type 316L stainless steel, designated as UNS S31603, is the low carbon version of Type 316. It has a reduced carbon content compared to its counterpart, which helps in minimizing deleterious carbide precipitation as a result of welding. Consequently, 316L is commonly used when welding is required to ensure maximum corrosion resistance. The lower carbon content of 316L makes it slightly more pliable and less prone to embrittlement compared to Type 316.

Standards and Specifications

  • European Standard: 316 is equivalent to 1.4401, 316L corresponds to 1.4404.
  • British Standard: 316S31 for Type 316, 316S11 for Type 316L.
  • ISO Standard: 316 as ISO 4401, 316L as ISO 4404.
  • ASTM Standard: ASTM A240 for both 316 and 316L.

Chemical Composition Of 316 Vs 316L Stainless Steel

Composition Overview

Both 316 and 316L stainless steel contain high levels of chromium and nickel, which are instrumental in enhancing their corrosion resistance. Chromium forms a passive layer of chromium oxide on the surface of the steel when exposed to oxygen, acting as a shield against corrosion. Nickel contributes to the stability of the austenitic structure of the steel, improving its overall ductility and resistance to a wide range of chemical environments.

Key Differences

  • Type 316 stainless steel has a maximum carbon content of 0.08%, while 316L has a reduced maximum carbon content of 0.03%.
  • The lower carbon content in 316L minimizes the risk of carbide precipitation during welding, making it ideal for applications involving extensive welding.
  • Both 316 and 316L contain molybdenum in a range of 2-3%, which increases their resistance to chlorides and other industrial solvents.

316 vs 316L Corrosion Resistance

Corrosion Resistance Factors

Stainless steel 316, also known as marine grade stainless steel, contains molybdenum that enhances its resistance to corrosion in marine and chemically aggressive environments. The presence of molybdenum in Type 316 improves the alloy’s resistance to chlorides and other industrial solvents.

Intergranular Corrosion

316L, with its lower carbon content, minimizes the risk of intergranular corrosion, particularly after welding. Intergranular corrosion is a selective attack in the grain boundary of stainless steel, which can lead to a deterioration in structural integrity.

Pitting and Crevice Corrosion

Both 316 and 316L are effective in resisting pitting and crevice corrosion, particularly in environments high in chlorides such as coastal areas or where de-icing salts are used.

304L vs 316L Strength

Strength Comparison

304L stainless steel, similar to 316L, is a low-carbon variant. However, 316L generally offers better overall corrosion resistance and is more resistant to pitting and crevice corrosion in chloride environments.

Tensile Strength

The tensile strength of 304L stainless steel is about 485 MPa, while 316L stainless steel typically ranges from 485 to 1700 MPa.

Applications

316L is often preferred in marine environments and applications involving exposure to chlorides, while 304L can be a cost-effective option in less aggressive environments and where slightly higher strength is needed.

316 versus 316L Stainless Steel: Mechanical Properties

Mechanical Property Overview

Type 316 stainless steel generally exhibits higher strength and hardness compared to 316L. The tensile strength of 316 stainless steel typically ranges from 515 to 690 MPa, whereas 316L stainless steel usually falls between 485 to 630 MPa.

Yield Strength

Type 316 stainless steel has a yield strength of about 205 MPa, while 316L typically has a slightly lower yield strength of about 170 MPa.

Impact Resistance

Both grades maintain excellent toughness even at cryogenic temperatures, making them ideal for use in harsh environments.

316 vs 316L Stainless Steel Machinability

Machinability Overview

Generally, Type 316 stainless steel is considered to have marginally better machinability than 316L due to its higher carbon content. However, both types can be effectively machined using modern techniques and optimized cutting tools.

Machining Considerations

  • Optimized cutting tools and machining parameters can mitigate many difficulties associated with machining 316 and 316L stainless steels.
  • Modifications in chemical composition, such as adding sulfur or selenium, can enhance machinability but may affect corrosion resistance.

Common Applications Of Stainless Steel 316 And 316L

Marine and Coastal Environments

Stainless steel 316 is extensively used in marine applications, including boat fittings, jetty fixtures, and offshore oil and gas rigs, where materials are exposed to harsher, corrosive environments.

Pharmaceutical and Food Processing Industries

The chemical composition of 316 stainless steel makes it suitable for use in the pharmaceutical and food processing industries. Its resistance to acids and bases at high temperatures makes it ideal for processing equipment.

Medical Field

Both 316 and 316L stainless steels are employed in the medical field for surgical instruments, implantable devices, and orthopedic pins and screws due to their robust anti-corrosive properties and superior strength.

Laboratory Equipment

316L stainless steel is preferred in the construction of laboratory equipment, including in chemical and petrochemical laboratories, due to its resistance to highly corrosive substances.

Summary Chart of What is the Difference Between 316 And 316L Stainless Steel

Property316 Stainless Steel316L Stainless Steel
Carbon ContentMax 0.08%Max 0.03%
Corrosion ResistanceHighHigher after welding
Tensile Strength515-690 MPa485-630 MPa
Yield Strength205 MPa170 MPa
ApplicationsMarine, Chemical, PharmaceuticalWelded Structures, Medical Equipment

Conclusion

In conclusion, the primary difference between Stainless Steel 316 and 316L lies in their carbon content; 316 has a higher carbon content while 316L has a lower level, making 316L more weldable and having slightly better corrosion resistance. Both types are durable, highly resistant to corrosion, and suitable for a wide range of applications, but the choice between 316 and 316L depends on specific requirements regarding strength, welding needs, and environmental conditions.

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